Wednesday, April 2, 2008 : 8:40 a.m.

Differential rates of PCE declines in a sand and gravel aquifer

Philip T. Harte, USGS WRD

Remediation of a sand and gravel aquifer contaminated with tetrachloroethylene (PCE) has resulted in several orders of magnitude declines in PCE concentrations in the primary source area to the Savage Superfund site in New Hampshire. PCE concentrations in 2006 declined below the target level of 2 parts per billion (ppb)) at some locations indicating that the remedial system, a low permeability containment wall and extraction wells, is effectively remediating the aquifer at those locations. However at other locations, PCE concentrations remain high (above 500 ppb).

 

Identification of layers of recalcitrant PCE were mapped with repeated vertical profiling and with repeated well sampling. In the absence of a source term, rates of PCE decline are governed by attenuation processes affecting the PCE. Results from the vertical profiling show high variability in rates of PCE declines. PCE declines can be described with a first order rate constant of -0.29 to -0.71 per year over parts of the aquifer; however, some layers show negligible changes over several years, indicating a potential source is present.

 

The distribution of the recalcitrant layers was mapped vertically by analyzing borehole gamma logs in conjunction with PCE concentrations. Borehole gamma logs measure radioactive decay of several elements and can indicate sediment grain size. At several locations, recalcitrant PCE concentrations correlated with large changes in gamma signals, suggesting the presence of stratigraphic contacts. Lithologic data collected during test drilling corroborated that gamma signal changes are due to lithologic variation. The highest PCE concentrations occurred within well sorted sands and gravels situated above relatively poorly sorted, less permeable sediments. The occurrence of the highest PCE concentrations within the more permeable layers suggests that either a residual PCE source is located above the less permeable layers or residual PCE is vertically migrating into the permeable layer from the less permeable layers.

Philip T. Harte, USGS WRD Philip T. Harte is a research hydrologist with the USGS (U.S. Geological Survey, NH/VT District, 361 Commerce Way, Pembroke, NH 03275; 603-226-7813; ptharte@usgs.gov). He has a bachelors degree in Geology from CUNY Queens College and a MS in Hydrology from the University of New Hampshire. As a hydrologist with the USGS, he has over 25 years of experience in ground-water flow and chemical transport studies. He also has worked as an environmental specialist with the U.S. Naval Reserve.


2008 Ground Water Summit