Thomas Ptak1, Maria Herold
1, Matthias Piepenbrink
2 and Peter Grathwohl
3, (1)University of Goettingen, (2)University of Darmstadt, (3)University of Tuebingen
At the ‘Testfeld-Süd’ (TFS) experimental site, a former gasworks site in southern Germany, ongoing research activities are focusing on the field scale quantitative determination of the in-situ natural attenuation potential of compounds such as BTEX, PAH and HET (N-S-O heteroaromatic compounds) that can typically be found in groundwater in case of tar oil subsurface contamination.
The quantification is performed using an integral investigation approach at multiple control planes (integral pumping tests, based on a numerical inversion of contaminant concentration time series measured during pumping), which are positioned at three different distances downgradient of the source zone, with a spacing of about 150 m. Natural attenuation processes result in a reduction of the total contaminant mass flow with increasing transport distance. Degradation rates can be obtained from multi-process-based reactive transport modeling which considers all processes (sorption, volatilization etc.) contributing to mass flow reduction.
The results from the integral investigation approach were compared to contaminant mass flow rate estimates obtained from point scale concentration measurements within a closely spaced direct-push monitoring well fence. The usually employed point scale approach is subject to a certain degree of uncertainty due to the required interpolation of point scale concentration values. In comparison, as a consequence of its integrating nature, the pumping test based investigation approach provides site assessment at a high level of certainty, especially at large polluted sites with a complex contamination pattern within the aquifer. However, more effort due to pumping is required, compared to the point scale measurements.
The comparison results suggest that unless a dense monitoring well network is available, only the integral investigation method presented can yield adequate results for the quantification of contaminant mass flow rates, especially at sites with heterogeneous aquifer conditions.
The 2007 Ground Water Summit