2007 Ground Water Summit

Monday, April 30, 2007 : 9:30 a.m.

Chloride in Ground Water and Surface Water in the Northern United States

John R. Mullaney, David Lorenz and Alan Arntson, U.S. Geological Survey

An analysis of the effects of deicing chemicals on ground-water and surface-water quality was conducted for the glacial aquifer system of the northern United States by analyzing data collected for the National Water Quality Assessment program from 1991-2004.

Concentrations of chloride were greater than the Secondary Maximum Contaminant Level (250 mg/L) in 2.3 percent of the samples from 869 monitoring wells, and 1.8 percent of the samples collected from 532 drinking water supply wells. Sodium concentrations were greater than the Drinking Water Advisory of 20 mg/L in samples from 56.7 percent of monitoring wells in urban areas, 16.9 percent of samples from monitoring wells in agricultural areas, and 7.3 percent of the monitoring wells in forested areas.  Sodium concentrations were greater than the Drinking Water Advisory in 47.5 percent of samples from public drinking water wells and 34.4 percent of private drinking-water wells.

An analysis of chloride-bromide ratios and chloride concentrations in samples from monitoring wells and drinking water wells indicated mixed sources of chloride (including halite dissolution and sewage or animal waste) in many of the samples, but higher concentrations were dominated by halite dissolution.

Surface-water quality data were analyzed from 31 urban and 20 forested basins.  Eleven of the urban basins contained major wastewater discharges. Twelve of the 51 sites had chloride concentrations greater than the U.S. Environmental Protection Agency recommended chronic aquatic criteria concentration of 230 mg/L. Concentrations of chloride exceeding the chronic criteria typically occurred during the winter months, indicating a possible relation with road deicing.  Base-flow chloride concentrations greater than 75 mg/L were indicative of sites with maximum measured chloride concentrations greater than 230 mg/L.  The median yield of chloride was 86 tons per square mile per year from the urban basins and 7 tons per square mile per year from the forested basins. 

John R. Mullaney, U.S. Geological Survey John Mullaney is a hydrologist in the USGS Connecticut Water Science Center. Over the last 20 years he has worked on a variety of projects that relate land use to ground-water and surface water quality

David Lorenz, U.S. Geological Survey David Lorenz is a hydrologist with the US Geological Survey, specializing in surface water and water-quality studies. Since 1991, he has been involved with local, regional, and national aspects of the National Water-Quality Assessment Program of the USGS.

Alan Arntson, U.S. Geological Survey Mr. Arntson earned a Bachelor of Civil Engineering degree from the University of Minnesota. He has been a hydrologist with the U. S. Geological Survey in Minnesota for 30 years and has worked on a variety of hydraulic and hydrologic studies from step-backwater models to watershed system models


The 2007 Ground Water Summit