, Pasi P. Hellstén and Taina H. Nystén, Ph.D., Finnish Environment Institute
In 2002, application of potassium formate
as a sole deicing agent was started on a stretch of a highway in Finland.
Prior to that, from 1977 to 2002, the stretch had been deiced with sodium
chloride. Microbial degradation of formate at low
temperatures in the top soil in the vicinity of the highway results in a rapid
removal of formate in the environment. Up to 96 % of 14C-formate
was degraded to 14CO2 within 1 day in the road side soil
samples at -2 oC to +6 oC.
Consequently, no formate has been detected in the
groundwater by September 2007. Chloride concentrations in the groundwater
underlying the highway show mostly decreasing trends. However, in the wells
with the highest chloride concentrations (up to 320 mg/L, which exceeds the
natural background chloride concentration by a factor of 100), chloride
concentrations increased or remained high until 2005-2006. In conclusion,
potassium formate can be applied in winter road
deicing at areas where the impacts of deicing on groundwater quality need to minimized.