Large Scale Pilot Studies Using Potassium Permanganate for In Situ Chemical Oxidation of Trichloroethylene in a Deep Desert Aquifer

Wednesday, April 22, 2009: 3:35 p.m.
Agave Ballroom (Hilton Tucson El Conquistador Golf & Tennis Resort )
Tim J. Allen , Errol L. Montgomery & Associates Inc., Tucson, AZ
Joseph R. Baker , Errol L Montgomery & Associates Inc., Tucson, AZ
Leslie Katz , Errol L. Montgomery & Associates Inc., Tucson, AZ
In-situ chemical oxidation (ISCO) using potassium permanganate has been successfully pilot tested for remediation of trichloroethylene (TCE) within the upper zone of the regional aquifer at two former solvent disposal sites at Air Force Plant 44 (AFP-44), in Tucson, Arizona.  Despite operation of a pump and treat groundwater remediation system since 1987 and a soil vapor extraction (SVE) system since 1995, TCE concentrations in groundwater remained large.  It was determined that sorbed and immiscible-phase TCE in fine-grained alluvial subunits was the source of elevated TCE concentrations in groundwater below former disposal sites.

Bench-scale laboratory tests and single well injection pilot tests were conducted in 2000 at two locations.   Subsequently, a large scale pilot test was conducted to treat a 12-acre portion of one of the former solvent disposal sites. Injection techniques and monitoring methods were optimized based on earlier pilot tests, resulting in increased efficiency and cost savings.

During the period 2004 through 2006, a second large-scale pilot test was conducted to treat a 21-acre portion of another former solvent disposal location.  TCE concentrations dropped below the detection limit in most wells during both large-scale pilot tests, followed by some rebound. However, post-test TCE concentrations in groundwater remain significantly below pre-test concentrations at both sites.

Important differences between ISCO tests at previous sites and testing conducted at AFP-44 include the lower levels of aqueous phase TCE, larger depth of contamination, and increased heterogeneity of the aquifer materials present at AFP-44, as well as the ISCO application methods employed at the site.  Low organic carbon content of the alluvial aquifer material is believed to have been a factor in program success. Based on experience at AFP-44, ISCO using potassium permanganate is a cost effective method for destruction of residual TCE in deep, low organic content, desert aquifers.