Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection, and Remediation® Conference

Tuesday, November 4, 2008 : 1:55 p.m.

Evaluation of Air Sparging Trench for the Treatment of VOCs and Arsenic

Michael C. Marley1, Omer Uppal1, Dennis Keane1 and Dean Peschel2, (1)XDD LLC, (2)City of Dover

An air sparging trench alternative was compared to a capping/pump and treat remedy for groundwater impacted with volatile organic compounds (VOCs) and arsenic constituents of concern (COCs), as specified in a Record of Decision (ROD) at a United States Environmental Protection Agency (USEPA) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) landfill site. The air sparging trench with an engineered backfill material was designed to intercept and treat COCs migrating with groundwater from beneath the landfill. The design and performance evaluation of the trench are presented.

 The trench was designed to provide in-situ flow-through treatment of VOCs by a combination of volatilization and aerobic biodegradation, and arsenic by precipitation and sorption. Various laboratory and field-scale tests were performed to evaluate the effectiveness of the trench in removing COCs. The results of laboratory, field-scale testing, and a stripping analysis indicated that the trench could remove the majority of VOCs that are present at the site by air sparging. Organic compounds that are not expected to be completely volatilized were projected to degrade by aerobic microorganisms in the oxygenated groundwater within and down-gradient of the trench.

 Geochemical modeling was performed to evaluate the ability of oxidizing conditions within trench to remove dissolved arsenic from groundwater through co-precipitation and sorption onto iron oxides. The modeling results indicated that oxidizing conditions created in the trench will result in precipitation of dissolved arsenic and other reduced minerals into the void spaces of the trench backfill material, significantly reducing the dissolved arsenic levels down-gradient of the trench.

 Long-term performance issues (i.e., mineral precipitation and biofouling) observed at other air sparging trenches were evaluated and solutions for such potential issues were incorporated in the design.  The air sparging trench alternative evaluation resulted in an amendment of the original ROD with a substantial cost saving to the client.

Michael C. Marley, XDD LLC Mr. Marley has over 30 years of experience in environmental and civil engineering. Mr. Marley is a nationally-known expert who focuses on strategies for site closure, including the development and application of innovative remediation technologies for contaminated soils and ground water. He has been at the forefront of developing design and application protocols for soil vapor extraction, air sparging and most recently in-situ chemical oxidation (ISCO) technologies. He has been responsible for the modeling support, review or design of several hundred pilot and full scale remediation systems as well as the completion of numerous bench scale treatability studies.


Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection, and Remediation® Conference